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Abstract In this paper we describe the long‐time behavior of the non‐cutoff Boltzmann equation with soft potentials near a global Maxwellian background on the whole space in the weakly collisional limit (that is, infinite Knudsen number ). Specifically, we prove that for initial data sufficiently small (independent of the Knudsen number), the solution displays several dynamics caused by the phase mixing/dispersive effects of the transport operator and its interplay with the singular collision operator. For ‐wavenumbers with , one sees anenhanced dissipationeffect wherein the characteristic decay time‐scale is accelerated to , where is the singularity of the kernel ( being the Landau collision operator, which is also included in our analysis); for , one seesTaylor dispersion, wherein the decay time‐scale is accelerated to . Additionally, we prove almost uniform phase mixing estimates. For macroscopic quantities such as the density , these bounds imply almost uniform‐in‐ decay of in due to phase mixing and dispersive decay.